Intramolecular noncovalent trans ring restricting free rotation of σ single bond enhances photosynthesis of hydrogen peroxide

Proceedings of the National Academy of Sciences, Volume 123, Issue 6, February 2026.
SignificanceCovalent organic frameworks (COFs) offer a promising molecular platform for the direct solar-to-chemical conversion of atmospheric oxygen and water into hydrogen peroxide (H2O2). Nevertheless, photogenerated charge carrier recombination …
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